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ChemInform Abstract: Stereochemical Study on Cyclic Acetal Formation During Anodic Oxidation of Naphthalene Derivatives by Transformation of Chiral Alcohol to Achiral Acetal.

✍ Scribed by M. FUJITA; M. OHSHIBA; S. SHIOYAMA; T. SUGIMURA; A. TAI


Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis


Stereochemical Study on Cyclic Acetal Formation During Anodic

Oxidation of Naphthalene Derivatives by Transformation of Chiral Alcohol to Achiral Acetal.

-A novel stereochemical approach named 'chiral eclipse' methodology is employed in anodic oxidation of chiral naphthalene derivatives to discriminate the intramolecular radical addition vs. intermolecular radical addition paths. -(FUJITA, M.; OHSHIBA, M.;