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ChemInform Abstract: Stereochemical Assignment of 2,3-Epoxy-2-methylbutanoate Esters in Natural Products

✍ Scribed by J. Martin Torres-Valencia; Carlos M. Cerda-Garcia-Rojas; Pedro Joseph-Nathan

Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
31
Category
Article
ISSN
0931-7597

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Stereochemical assignment of 2,3-epoxy-2
Stereochemical assignment of 2,3-epoxy-2-methylbutanoate esters in natural products
✍ J. MartΓ­n Torres-Valencia; Carlos M. Cerda-GarcΓ­a-Rojas; Pedro Joseph-Nathan πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 213 KB

Inspection of the 182 known natural products containing 2,3-epoxy-2-methylbutanoate ester residues revealed a very high tendency in nature for the preferential epoxidation of (Z)-2-methyl-2-butenoate esters (angelates) over (E)-2-methyl-2-butenoate esters (tiglates), since 177 compounds contain epox