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ChemInform Abstract: Stabilizing Low-Valent Refractory Metals in a Strongly Oxidizing Medium: The First Molybdenum(V) Sulfate - MoO(HSO4)(SO4) - From Mo(CO)6 in Oleum.

✍ Scribed by Ulf Betke; Kai Neuschulz; Mathias S. Wickleder


Publisher
John Wiley and Sons
Year
2011
Weight
21 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

Deep‐blue single crystals of MoO(HSO~4~)(SO~4~) are prepared from Mo(CO)~6~ in oleum (sealed glass ampule, 200 °C, 2 d).