Sr 5 [NbN 4 ]N (transparent, red single crystals) was synthesized by reaction of Sr 2 N with Nb under nitrogen at ambient pressure and 1223 K. The crystal structure was solved and refined in the space group Pbcm (no. 57), Z ϭ 4, with lattice constants a ϭ 646.6(3) pm, b ϭ 1792.5(9) pm, c ϭ 729.8(4)
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ChemInform Abstract: Sr5[NbN4]N — A Nitridoniobate(V) Nitride Containing Isolated [NbN4]7- Tetrahedra and Octahedral Chains ∞1 (Sr4Sr2/2N7+).
✍ Scribed by Peter Hoehn; Ruediger Kniep
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 33 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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