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ChemInform Abstract: Spectroscopic Properties of KY3F10:Er3+.

✍ Scribed by K. HEYDE; K. BINNEMANS; C. GOERLLER-WALRAND

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

1998 spectra spectra (general) (solids and liquids) D 6500

34 -003

Spectroscopic Properties of KY 3 F 10 :Er 3+ .

-Using absorption, luminescence, and MCD spectra, a part of the 4f 11 configuration of Er 3+ in the cubic host crystal KY 3 F 10 can be reconstructed. The three mutually perpendicular sites with C 4v symmetry result in three different sets of crystal-field parameters, which can be related to each other by transformation formulae. Although the A Ξ» tp intensity parameters can describe the experimental dipole strengths quite well, the complexity of the KY 3 F 10 :Er 3+ matrix does not allow an accurate simulation of the MCD spectrum. -(HEYDE, K.; BINNEMANS,

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