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ChemInform Abstract: Some Transformations of Adducts of 3,6-Dimethoxy-4,5-methylenedioxy-1,2-didehydrobenzene and Furans. An Approach to the 5,8-Dimethoxy-6,7-methylenedioxynaphtho[2,3-c]furan-4,9-dione Ring System of Ventilone A.

✍ Scribed by J. H. BUTTERY; D. WEGE

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: A Novel Synthetic M
ChemInform Abstract: A Novel Synthetic Method of the (VII) (.+-.)-(3aα,8aα)-Ethyl 8β-Hydroxy-6β-methyl-2-oxooctahydro-2H-cyclohepta [b]furan-3α-carboxylate and Its Chemical Transformation to (XIII) (.+-.)-(3aα,8aα) -3α,6β-Dimethyl-3,3a,4,5,6,8a-hexahydro-2H-cyclohepta [b]furan-2-one, (+)- (XIV) and (-)- (XIV) -7β-(2-Acetoxy-1α-methylethyl) -4β-methyl-2-cyclohepten-1β-ol, and (+)- (XVII) and (-)- (XVII) -7β-(2-Acetoxy-1α-methylethyl) -4β-methyl-2-cyclohepten-1-one. Possible Common Synthetic Intermediates for Pseudoguaianolides, 4,5-Secopseudoguaianolides, Guaianolides, 4,5-Secoguaianolides, and Octalactins.
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