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ChemInform Abstract: Solvent-Free Reactions of Alcohols with β-Dicarbonyl Compounds Catalyzed by Iron(III) Chloride.

✍ Scribed by Yu Yuan; Zhuangzhi Shi; Xuan Feng; Xiangnong Liu

Publisher
John Wiley and Sons
Year
2008
Weight
38 KB
Volume
39
Category
Article
ISSN
0931-7597

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Solvent-free reactions of alcohols with
Solvent-free reactions of alcohols with β-dicarbonyl compounds catalyzed by iron(III) chloride
✍ Yu Yuan; Zhuangzhi Shi; Xuan Feng; Xiangnong Liu 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 142 KB 👁 1 views

## Abstract The direct substitution of alcohols and β‐dicarbonyl compounds was catalyzed with FeCl~3~ under solvent‐free conditions. The catalyst loading could be decreased to 0.01 mol% at high activities. It was shown that the reaction proceeded in two steps via the etherification of the alcohols.