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ChemInform Abstract: Solid-State Diastereoselective Formation of Oxazolidines.

✍ Scribed by N. S. KHRUSCHEVA; N. M. LOIM; V. I. SOKOLOV; V. D. MAKHAEV

Publisher: John Wiley and Sons
Year: 2010
Weight: 28 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199750044

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✦ Synopsis

Solid-State Diastereoselective Formation of Oxazolidines.

-A number of organic and organometallic aldehydes are converted into optically active oxazolidines (III) and (V) by solid-state interaction with (-)-ephedrine (II) and (+)-pseudoephedrine (IV), respectively. In general, the new chiral center is formed with a high degree of diastereoselectivity. The same results are obtained in boiling EtOH. -(KHRUSCHEVA, N.

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