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ChemInform Abstract: Sol-Gel Derived Hybrid Materials as Heterogeneous Catalysts for the Synthesis of N,N-Dimethylformamide from Supercritical Carbon Dioxide

✍ Scribed by O. KROECHER; R. A. KOEPPEL; A. BAIKER


Book ID
112039899
Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
27
Category
Article
ISSN
0931-7597

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✍ Oliver Kröcher; René A. Köppel; Alfons Baiker 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 198 KB

The synthesis of N,N-dimethylformamide from carbon dioxide, hydrogen and dimethylamine has been studied in an Ä Ž . Ž . 4 Ž . autoclave using a sol-gel derived heterogeneous catalyst made of RuCl PPh CH Si OEt and Si OEt in a ratio of 2 2 2 2 33 4 1:50. The effect of the reaction variables on the ac