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ChemInform Abstract: Sodium Nitrite (NaNO2) Catalyzed Iodo-Cyclization of Alkenes and Alkynes Using Molecular Oxygen.

✍ Scribed by Hongjun Liu; Yuanhang Pan; Choon-Hong Tan

Book ID: 102022145
Publisher: John Wiley and Sons
Year: 2008
Weight: 48 KB
Volume: 39
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200842088

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Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

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## Abstract Palladium(II) acts as a one‐pot catalyst to promote the oxidation of alkynes (I) with atmospheric oxygen as the sole oxidant in a fluorous biphasic system, followed by a cyclization reaction which results in the direct conversion of alkynes into tetrasubstituted furans (II).