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ChemInform Abstract: Simple and Efficient Resolution of 1,1′-Bi-2-naphthol.

✍ Scribed by D. CAI; D. L. HUGHES; T. R. VERHOEVEN; P. J. REIDER


Book ID
112027823
Publisher
John Wiley and Sons
Year
2010
Weight
24 KB
Volume
27
Category
Article
ISSN
0931-7597

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Efficient synthesis of 6-mono-bromo-1,1′
✍ Dongwei Cai; Robert D Larsen; Paul J Reider 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 73 KB

Through mono-ester formation of 1,1%-bi-2-naphthol (BINOL) with pivaloyl chloride the selective mono-bromination was achieved cleanly on the other ring to afford 6-mono-bromo-1,1%-bi-2-naphthol in an efficient 86% yield.