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ChemInform Abstract: Silver-Catalyzed Cyclization of Acetylenic Alcohols: Synthesis of Functionalized 2-Methylene-oxolanes.

✍ Scribed by Patrick Pale; Josselin Chuche


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
31
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Silver-Catalyzed Cyclization of Acetylen
✍ Patrick Pale; Josselin Chuche πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 287 KB

Silver salts which have a basic counter-ion are efficient catalysts for the regiospecific intramolecular addition of various acetylenic alcohols. Silver carbonate in aromatic solvent proved to be the best catalyst. Alkynols in which the two reacting parts of the molecule are relatively close togethe