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ChemInform Abstract: Silicon-Mediated Synthesis and Selected Transformations of β-Chloroketones.

✍ Scribed by Tarek A. Salama; Saad S. Elmorsy

Publisher
John Wiley and Sons
Year
2012
Weight
29 KB
Volume
43
Category
Article
ISSN
0931-7597

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Enediolates and Dienediolates of Carboxylic Acids in Synthesis. Synthesis of β,γ-Epoxyacids from α-Chloroketones. -Lithium dienolates of saturated acids (I) and (XII) react with α-chloroketones to produce highly substituted β,γ-epoxyacids as the major products in most cases. Unsaturated acids such a