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ChemInform Abstract: Selective Wittig Olefination in Aqueous Media for the Rapid Preparation of Unsaturated 7,3-Lactone-α-D-xylofuranose Derivatives.

✍ Scribed by Elsie Ramirez; Mario Sanchez; Rosa L. Meza-Leon; Leticia Quintero; Fernando Sartillo-Piscil

Book ID
102048281
Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
41
Category
Article
ISSN
0931-7597

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Selective Wittig olefination in aqueous
Selective Wittig olefination in aqueous media for the rapid preparation of unsaturated 7,3-lactone-α-d-xylofuranose derivatives
✍ Elsie Ramirez; Mario Sánchez; Rosa L. Meza-León; Leticia Quintero; Fernando Sart 📂 Article 📅 2010 🏛 Elsevier Science 🌐 French ⚖ 312 KB

A highly efficient and rapid protocol for the preparation of the title compounds 1a and 1b from D-glucose derivatives 2a and 2b, respectively, is reported. To this end, highly selective Wittig olefination in aqueous media was developed for the elaboration of a,b-unsaturated acids 5a and 5b, which wh