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ChemInform Abstract: Selective Synthesis of 1,4-Dialkylbenzenes from Terephthalic Acid.

✍ Scribed by Andrea Bramborg; Torsten Linker


Publisher
John Wiley and Sons
Year
2011
Weight
38 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

Terephthalic acid reacts with alkyl halides under Birch conditions to substituted 1,4‐cyclohexadienes.


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The synthesis and analysis of copolyesters based on 1,4: 3,6-dianhydrosorbitol (DAS), ethylene glycol, and terephthalic acid is described. It is shown that these copolyesters present materials stable up to elevated temperatures. The glass transition temperature, Tg, is shown to rise linearly with in