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ChemInform Abstract: Selective Mono- and 1,2-Difunctionalization of Cyclopentene Derivatives via Mg and Cu Intermediates.

✍ Scribed by Christina Despotopoulou; Richard C. Bauer; Arkady Krasovskiy; Peter Mayer; Jeffrey M. Stryker; Paul Knochel

Publisher: John Wiley and Sons
Year: 2008
Weight: 72 KB
Volume: 39
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200828065

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Mono and Difunctionalization of Chiral Ferrocenyl Bisacetals. X-Ray Crystal Structure of Bis-1,1'-[(2S,4S)-(hydroxymethyl)-2-dioxane1,3]ferrocene. -The title chiral bisacetals (III) and (V) react with tBuLi and MeLi to the o-Li compounds, which are converted with electrophiles like (VI) to o-substit