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ChemInform Abstract: Selective Aryl Coupling via Palladacycles: A New Route to m-Alkylbiphenyls or m-Terphenyls.

✍ Scribed by M. CATELLANI; E. MOTTI

Book ID
101872046
Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

I), (V), and (VII) (applied as their dimers) are regioselectively arylated with iodides (II) to give the corresponding intermediate biphenyl-and terphenylpalladium complexes. They are demetalated by hydrogenolysis. The formation of by-products can be avoided if the reaction is carried out in vacuo. The anomalous behavior of complex (VII) is attributed to the steric bulkiness of the tert-butyl group. -(CATELLANI,

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