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ChemInform Abstract: Secondary—Secondary Diamine Catalysts for the Enantioselective Michael Addition of Cyclic Ketones to Nitroalkenes.

✍ Scribed by Sunil V. Pansare; Raie Lene Kirby

Publisher: John Wiley and Sons
Year: 2009
Weight: 28 KB
Volume: 40
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200939026

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## Diastereo-and Enantioselective Synthesis of Vicinal Diamines via Aza-Michael Addition to Nitroalkenes. -Key step in the diastereoand enantioselective synthesis of vicinal diamines is an auxiliary-controlled diastereoselective conjugate addition of a chiral ammonia equivalent (II) to nitroalken