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ChemInform Abstract: Scandium-Mediated Opening of Aziridine Carboxylates: A Facile Synthesis of Aryl-Substituted Tryptophans.

✍ Scribed by Y. L. BENNANI; G.-D. ZHU; J. C. FREEMAN

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Scandium-Mediated Opening of Aziridine Carboxylates: A Facile Synthesis of Aryl-Substituted Tryptophans.

-Indoles (I) react with enantiopure N-protected aziridines (II) derived from L-serine in the presence of stoichiometric amounts of scandium triflate. Aryl-substituted and -protected tryptophans (III) are isolated in fair to good yields. -(BENNANI, Y. L.;

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