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ChemInform Abstract: Ruthenium Tetraoxide Oxidation of Alkenes. Part 7. A More Complete Picture.

✍ Scribed by L. ALBARELLA; V. PICCIALLI; D. SMALDONE; D. SICA

Publisher: John Wiley and Sons
Year: 2010
Weight: 35 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199703098

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✦ Synopsis

Part 7. A More Complete Picture.

-The main oxidation products of a number of linear and cyclic alkenes are 1,2-diols and/or α-ketols sometimes accompanied by small amounts of scission products such as aldehydes and/or ketones which can be further oxidized to carboxylic acids or can react with the diols to form cyclic acetals, e.g. (XVIII). All reactions proceed through a common intermediate ruthenium(VI) diester, which is presumably the first-formed product from a (3 + 2) cycloaddition of RuO4 to the olefin. -(ALBARELLA, L.; PICCIALLI,

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