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ChemInform Abstract: Ruthenium-Catalyzed Stereoselective anti-Markovnikov Addition of Thioamides to Alkynes.

✍ Scribed by Lukas J. Goossen; Mathieu Blanchot; Kifah S. M. Salih; Ralf Karch; Andreas Rivas-Nass

Publisher: John Wiley and Sons
Year: 2009
Weight: 54 KB
Volume: 40
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200910078

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Ru-Catalyzed anti-Markovnikov Addition of Amides to Alkynes: A Regio- and Stereoselective Synthesis of Enamides.

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## Abstract For Abstract see ChemInform Abstract in Full Text.

Ru-Catalyzed Anti-Markovnikov Addition o

Ru-Catalyzed Anti-Markovnikov Addition of Amides to Alkynes: A Regio- and Stereoselective Synthesis of Enamides

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The enamide group is an important substructure that is often found in natural products [1] and synthetic drugs that have, amongst others, sedative, [2] cytotoxic, [3] or anti-inflammatory [4] properties. Moreover, they are versatile synthetic intermediates that can serve as substrates for polymeriza

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