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ChemInform Abstract: Ruthenium-Catalyzed Cyclization/Transfer Hydrogenation of 1,6-Diynes: Unprecedented Mode of Alcohol Activation via Metallacyclopentatriene.

✍ Scribed by Ken Yamashita; Yuki Nagashima; Yoshihiko Yamamoto; Hisao Nishiyama

Publisher
John Wiley and Sons
Year
2012
Weight
37 KB
Volume
43
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

The first transfer‐hydrogenative cyclization of 1,6‐diynes furnishing exocyclic dienes is developed using a Ru‐catalyst and MeOH as H~2~ surrogate.

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