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ChemInform Abstract: Room Temperature Catalytic Amination of Aryl Iodides.

✍ Scribed by J. P. WOLFE; S. L. BUCHWALD

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Room Temperature Catalytic Amination of Aryl Iodides.

-A general procedure for the synthesis of aryl amines such as (III) is developed, which has the advantage to proceed at room temperature. It is noteworthy that 2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl is also an effective catalyst, which gives similar results. Various kinds of solvents and additives are tested but THF/18-crown-6 leads to the highest yields. -(WOLFE,

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