ChemInform Abstract: Ring-Expansion of 2-Methylbenzo[b]furan to 3-Hydroxychromen-4-one: A Potential Approach to a Flavonol Skeleton.
β Scribed by T. ISHIKAWA; C. MIWA
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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Chemoenzymatic and Ring E-Modular Approach to the (-)-Podophyllotoxin Skeleton. Synthesis of 3',4',5'-Tridemethoxy-(-)-podophyllotoxin. -The first ring E deoxygenated derivative (XI) of the antimitotic (-)-podophyllotoxin (XII) is synthesized. The key steps are the introduction of the absolute ste