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ChemInform Abstract: Ring Closing Metathesis as an Efficient Approach to Branched Cyclitols and Aminocyclitols: A Short Synthesis of Valiolamine.

✍ Scribed by Odile Sellier; Pierre Van de Weghe; Didier Le Nouen; Christiane Strehler; Jacques Eustache

Publisher: John Wiley and Sons
Year: 2010
Weight: 33 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199921200

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✦ Synopsis

Ring Closing Metathesis as an Efficient Approach to Branched Cyclitols and Aminocyclitols: A Short Synthesis of Valiolamine.

-Ring-closing metathesis of sugar-derived 1,7-diene (VI) is the key step for the construction of highly functionalized cyclohexenes (VII) and (VIII), precursors of branched cyclitols and aminocyclitols. This method is used for a short synthesis of valiolamine (XII). -(SELLIER, ODILE; VAN DE WEGHE,

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