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ChemInform Abstract: Rhodium-Catalyzed Cyclopropanation of Alkenes with Dimethyl Diazomalonate.

✍ Scribed by Francisco Gonzales-Bobes; Michael D. B. Fenster; Susanne Kiau; Laxma Kolla; Sergei Kolotuchin; Maxime Soumeillant

Publisher: John Wiley and Sons
Year: 2008
Weight: 57 KB
Volume: 39
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200831042

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Rhodium-Catalyzed Cyclopropanation of Al

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ChemInform Abstract: Rhodium-Catalyzed Intramolecular Silylformylation of Alkenes.

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Rhodium-Catalyzed Intramolecular Silylformylation of Alkenes. -For the first time the silylformylation of alkenes is described. In every case the diastereomeric aldehydes are the major products. Small amounts of the diastereomeric hydrosilylation products are the only by-products. -(LEIGHTON,