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ChemInform Abstract: Rhodium-Catalyzed Coupling Reaction of Salicyl Aldehydes with Alkynes via Cleavage of the Aldehyde C—H Bond.

✍ Scribed by K. KOKUBO; K. MATSUMASA; M. MIURA; N. NOMURA

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Reaction of 2-Hydroxybenzaldehydes with Alkynes, Alkenes, or Allenes via Cleavage of the Aldehyde C—H Bond Using a Rhodium Catalyst System.
✍ Ken Kokubo; Kenji Matsumasa; Yuko Nishinaka; Masahiro Miura; Masakatsu Nomura 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

Reaction of 2-Hydroxybenzaldehydes with Alkynes, Alkenes, or Allenes via Cleavage of the Aldehyde C-H Bond Using a Rhodium Catalyst System. -Aldehyde (I) smoothly reacts with internal and terminal alkynes to give alkenoylphenols in good to excellent yields. The substituents of acetylene influence th