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ChemInform Abstract: Rhodium-Catalyzed Asymmetric Ring-Opening Alkynylation of Azabenzonorbornadienes.

✍ Scribed by Takahiro Nishimura; Eiji Tsurumaki; Takahiro Kawamoto; Xun-Xiang Guo; Tamio Hayashi

Publisher
John Wiley and Sons
Year
2009
Weight
35 KB
Volume
40
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Rhodium-Catalyzed A
ChemInform Abstract: Rhodium-Catalyzed Asymmetric Ring-Opening Reactions of N-Boc-Azabenzonorbornadiene with N-Substituted Piperazine Nucleophiles.
✍ Yuhua Long; Dingqiao Yang; Heping Zeng; Lei Xie; Lihuan Wu; Haihong Mo; Xiongjun πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 23 KB πŸ‘ 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

Rhodium-catalyzed Asymmetric Ring-openin
Rhodium-catalyzed Asymmetric Ring-opening Reactions of N-Boc-azabenzonorbornadiene with N-Substituted Piperazine Nucleophiles
✍ Yuhua Wu; Dingqiao Yang; Heping Zeng; Lei Xie; Lihuan Wu; Haihong Mo; Xiongjun Z πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 133 KB

## Abstract Asymmetric ring‐opening reactions of __N__‐Boc‐azabenzonorbornadiene with __N__‐substituted piperazine nucleophiles in the presence of 5 mol% of [Rh(COD)Cl]~2~ and 10 mol% of chiral ligand, (__R__,__S__)‐PPF‐P‐__t__‐Bu~2~, gave the corresponding 1,2‐diamine product in moderate to excell