ChemInform Abstract: Rhenium(I)-Catalyzed Cyclization of Silyl Enol Ethers Containing a Propargyl Carboxylate Moiety: Versatile Access to Highly Substituted Phenols.

✍ Scribed by Kodai Saito; Yuji Onizawa; Hiroyuki Kusama; Nobuharu Iwasawa

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 28 KB
• Volume: 41
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.201036069

✦ Synopsis

Abstract

Depending on the structure of the silyl enol ether moiety, either nucleophilic addition of the silyl enol ether moiety, or 1,2‐acyloxy migration occurs to give two kinds of substituted phenols.