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ChemInform Abstract: Remote Oxygen Migration Reaction Between Sulfur Atoms in 1,4-Bis(methylthio)benzene Derivatives: Possible Formation of Bis(dithia dication) Dimer as an Intermediate.

✍ Scribed by K. KOBAYASHI; T. OBINATA; N. FURUKAWA


Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis


Remote Oxygen Migration Reaction Between Sulfur Atoms in 1,4-Bis(methylthio)benzene Derivatives: Possible Formation of Bis(dithia dication) Dimer as an Intermediate.

-In TFA solution, the oxygen atom of the monosulfoxide of 1,4-bis(methylthio)benzene migrates from one sulfur atom to the other sulfur atom. The results are explained on the basis of the formation of a dimeric dication.

-(KOBAYASHI, K.; OBINATA,