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ChemInform Abstract: Remarkable Template Effect of a Lewis Acidic Receptor in Intramolecular Radical Cyclizations.

โœ Scribed by T. OOI; Y. HOKKE; K. MARUOKA


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Lewis Acid Promoted
โœ T. SHIMADA; Y. YAMAMOTO ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 29 KB

Lewis Acid Promoted Highly Diastereoselective Desymmetric Intramolecular Cyclization of Allylstannane with a Diketone. -The prochiral allylstannyl diketone (I) undergoes Lewis acid catalyzed desymmetric intramolecular cyclization. By proper choice of the Lewis acid a highly diastereoselective synth