ChemInform Abstract: Remarkable Effect of Phosphine on the Reactivity of O,P-Acetal—Efficient Substitution Reaction of O,P-Acetal.
✍ Scribed by Hiromichi Fujioka; Akihiro Goto; Kazuki Otake; Ozora Kubo; Kenzo Yahata; Yoshinari Sawama; Tomohiro Maegawa
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 35 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
Tri(o‐tolyl)phosphine is identified as a good nucleophile for the formation of intermediate O,P‐acetals from O,O‐acetals (I) and a good leaving group for the successive nucleophilic substitution.
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