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ChemInform Abstract: Regiospecificity in the Hydroboration of 6-Hydroxyandrost-4-enes.

โœ Scribed by J. R. HANSON; P. B. HITCHCOCK; M. D. LIMAN


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: A Novel Cyclization
โœ J. A. SODERQUIST; G. LEON ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 35 KB

A previously unknown process, the formation of 3-boryl-stannacyclopentane (III), is observed from monohydroboration of divinyldimethyltin (I) with 9-BBN. The product undergoes expected reactions of an organoborane with trimethylamine N-oxide, NaOH/H 2 O 2 , and benzaldehyde. However, attempted Suzuk