ChemInform Abstract: Regiospecific Synthesis of 1H,5H- and 3H,5H-Benzo(ij)quinolizin-5-one Derivatives.
β Scribed by P. RODIGHIERO; A. CHILIN; G. BANDOLI; P. MANZINI; A. CASTELLIN; A. GUIOTTO
- Book ID
- 112020882
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0931-7597
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## Abstract (__R__)β5β(diallylamino)β5,6βdihydroβ4__H__βimidazo[4,5,1β__ij__]quinolinβ2(1__H__)βone (__12b__) was prepared in 9% overall yield from 3βaminoquinoline. Reaction of __12b__ in ethyl acetate with tritium gas in presence of a 5% platinum on carbon catalyst afforded a mixture of (__R__)β5