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ChemInform Abstract: Regiospecific Substitution of N-Acyl-2,3-dihydro-4-pyridones at C-5 via Halogenation and Cross-Coupling.

✍ Scribed by D. L. COMINS; S. P. JOSEPH; X. CHEN

Book ID
112029903
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
27
Category
Article
ISSN
0931-7597

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ChemInform Abstract: C-3 Acetoxylation o
ChemInform Abstract: C-3 Acetoxylation of N-Acyl-2,3-dihydro-4-pyridones.
✍ D. L. COMINS; D. A. STOLZE; P. THAKKER; C. L. MCARDLE πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 28 KB πŸ‘ 2 views

C-3 Acetoxylation of N-Acyl-2,3-dihydro-4-pyridones. -Stereoselective C-3 acetoxylation of various N-acyldihydropyridones (I) is achieved under mild conditions using lead tetraacetate. The analogous reaction of the indolizidinone (IV) to the cis product proceeds with considerably lower yield.