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ChemInform Abstract: Regiospecific Rearrangement of Hydroxylamines to Secondary Amines Using Diisobutylaluminum Hydride.

✍ Scribed by Hidetsura Cho; Kenji Sugimoto; Yusuke Iwama; Nakako Mitsuhashi; Kentaro Okano; Hidetoshi Tokuyama

Publisher: John Wiley and Sons
Year: 2011
Weight: 35 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201129030

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✦ Synopsis

Abstract

The reductive ring expansion reaction of N‐monosubstituted hydroxylamines with DIBAL‐H proceeds regiospecifically providing cyclic secondary amines in moderate to good yields.

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ChemInform Abstract: Regiospecific Synthesis of Unsubstituted Basic Skeletons of Heterocycles Containing Nitrogen Neighboring an Aromatic Ring by the Reductive Ring Expansion Reaction Using Diisobutylaluminum Hydride.

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