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ChemInform Abstract: Regiospecific Aromatic Chlorination of Alkyl Phenyl Ethers Using Sodium Chlorite Catalyzed by Manganese(III) Acetylacetonate and Moist Alumina in Dichloromethane.

✍ Scribed by M. HIRANO; S. YAKABE; H. MONOBE; J. H. CLARK; T. MORIMOTO

Publisher: John Wiley and Sons
Year: 2010
Weight: 34 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199810067

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✦ Synopsis

The solid-solution biphasic system of NaClO 2 /moist alumina/Mn(acac) 3 serves as a mild and efficient electrophilic chlorine source for alkyl phenyl ethers, providing an operationally simple, fast and practical procedure for regioselective and high-yielding aromatic chlorination.

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