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ChemInform Abstract: Regiospecific Acylation of Acetals. A Convenient Method to Obtain β-Methoxyvinyl Trichloromethyl Ketones.

✍ Scribed by Marcos A. P. Martins; Giovani P. Bastos; Helio G. Bonacorso; Nilo Zanatta; Alex F. C. Flores; Geonir M. Siqueira

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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Regiospecific acylation of acetals. A co
Regiospecific acylation of acetals. A convenient method to obtain β-methoxyvinyl trichloromethyl ketones
✍ Marcos A.P. Martins; Giovani P. Bastos; Helio G. Bonacorso; Nilo Zanatta; Alex F 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 209 KB

The regiochemistry of the acylation of enol ethers, generated in situ, from acetals of unsymmetrical ketones is reported. These results demonstrate a convenient one-pot method to obtain a series of I~-methoxyvinyi trichloromethyl ketones [CCI3COCH=C(OMe)R, where R=Et, n-Bu, i-Pr, (CH2)2C(OMe)=CHC(O)

ChemInform Abstract: Trifluoroacetylatio
ChemInform Abstract: Trifluoroacetylation of Unsymmetrical Ketone Acetals. A Convenient Route to Obtain Alkyl Side Chain Trifluoromethylated Heterocycles.
✍ Helio G. Bonacorso; Marcos A. P. Martins; Sandra R. T. Bittencourt; Rogerio V. L 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB

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