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ChemInform Abstract: Regioselectivity of Electroreductive Transannular Reaction of 7-Methylenebicyclo[3.3.1]nonan-3-one.

✍ Scribed by Hiroki Itoh; Ichiro Kato; Kei Unoura; Yasuhisa Senda


Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
32
Category
Article
ISSN
0931-7597

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A Practical Synthesis of Bicyclo[3.3.1]nonan-9-one. -A new protocol for the synthesis of title compound (VII) is presented. It uses inexpensive and readily available reagents, involves no purification of intermediates and can be carried through on a β‰ˆ20 g product scale in 47% yield. -(TAESCHLER,