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ChemInform Abstract: Regioselective Synthesis of 3-Aryl Substituted Pyrrolidines via Palladium Catalyzed Arylation: Pharmacological Evaluation for Central Dopaminergic and Serotonergic Activity.

✍ Scribed by C. SONESSON; H. WIKSTROEM; M. W. SMITH; K. SVENSSON; A. CARLSSON; N. WATERS


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis


Serotonergic Activity. -A series of novel 3-arylpyrrolidines, e.g. (IV), (VI), and (VIII), is prepared for structure-activity relationship investigations of CNS stabilizers. The meta substitution at the aromatic ring seems to be necessary for good receptor binding activity. The use of monodentate phosphine ligands and choice of reaction temperature significantly suppress the formation of the undesired 2-arylpyrrolidines.