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ChemInform Abstract: Regioselective Monometalation of 2,5-Pyridinedicarboxamides with (2,2, 6,6-Tetramethylpiperidino)magnesium Chloride (TMPMgCl).

✍ Scribed by W. SCHLECKER; A. HUTH; E. OTTOW; J. MULZER


Book ID
112023807
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
26
Category
Article
ISSN
0931-7597

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Regioselective monometalation of 2,5-pyr
✍ Schlecker, Wolfgang ;Huth, Andreas ;Ottow, Eckhard ;Mulzer, Johann πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 691 KB

## Abstract The 2,5‐pyridinecarboxamides 9–15 were synthesized in one or two steps from diester 1 by addition of an excess of dimethylaluminium amide or successive addition of two different dimethylaluminium amides with or without intermediate workup. For the carboxamides 16 and 17 this method fail