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ChemInform Abstract: Regioselective Introduction of 2-Propynyl Groups into the C-2 or C-3 Position of Furanoside Ring.

โœ Scribed by D. KUBOTA; O. MITSUNOBU


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Regioselective Redu
โœ T. BACH; F. EILERS; K. KATHER ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 1 views

Regioselective Reductive Ring Opening of 2-(2-Hydroxyphenyl)-3-(( trimethylsilyl)oxy)oxetanes at the More Substituted C-2 Position. -The title compounds are prepared in situ by deprotection of the oxetanes (III) and (IV) with LiAlH4 in THF. Under these conditions a reductive ring opening occurs yiel