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ChemInform Abstract: Regioselective Haller-Bauer Cleavage in Tricyclo(5.2.1.02,6)dec-8-ene- 3,10-dione. A Total Synthesis of (.+-.)-Pumiliotoxin C.

✍ Scribed by G. MEHTA; M. PRAVEEN

Book ID
112023164
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
26
Category
Article
ISSN
0931-7597

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## Abstract 4‐[3‐[4‐(2‐Methoxyphenyl)piperazin‐1‐yl]propoxy]‐4‐aza‐tricyclo[5.2.1.02,6]dec‐8‐ene‐3,5‐dione (4), a potent and selective 5‐HT~1A~ agonist, was labeled by ^11^C‐methylation of the corresponding desmethyl analogue 3 with ^11^C‐methyl triflate. The precursor molecule 3 was synthesized fr