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ChemInform Abstract: Regioselective Amination of 3-Bromoindolylmaleimide with Amines.

โœ Scribed by Di-Fa Jiang; Yan-Wu Yang; Zhi-Yu Shao; Sheng-Yin Zhao

Book ID
102044174
Publisher
John Wiley and Sons
Year
2010
Weight
39 KB
Volume
41
Category
Article
ISSN
0931-7597

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Regioselective Acylation of Heterocyclic Ketene Aminals with Acetyl Chloride. -Acylation of ketene aminals (I) affords exclusively the N-acylated products (IV), while in the presence of triethylamine and Hg(CN)2 the C-acylated products (III) predominate together with (IV) as minor products. The (E)