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ChemInform Abstract: Regioselective Acylation of Hexopyranosides with Pivaloyl Chloride.

โœ Scribed by L. JIANG; T.-H. CHAN

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Regioselective Acyl
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โœ C.-Y. YU; Z.-T. HUANG; L.-B. WANG ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 29 KB ๐Ÿ‘ 1 views

Regioselective Acylation of Heterocyclic Ketene Aminals with Acetyl Chloride. -Acylation of ketene aminals (I) affords exclusively the N-acylated products (IV), while in the presence of triethylamine and Hg(CN)2 the C-acylated products (III) predominate together with (IV) as minor products. The (E)