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ChemInform Abstract: Regiochemistry and Stereochemistry of α,β-Epoxysilane Ring Opening with Silyl Halides or Pseudohalides.

✍ Scribed by A. R. BASSINDALE; M.-C. SOOBRAMANIEN; P. G. TAYLOR

Book ID
112024393
Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
26
Category
Article
ISSN
0931-7597

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✍ Michael R. Detty; Mark D. Seidler 📂 Article 📅 1982 🏛 Elsevier Science 🌐 French ⚖ 289 KB

The ring-opening of various styrene and stilbene oxides with silyl halides was examined. The regiochemistry of ring-opening was independent of the silyl halide used, but the stereochemistry of ring-opening was sensitive to both the choice of halide and the steric bulk of groups attached to silicon.