ChemInform Abstract: Regio- and Stereoselective Ring Opening of 2,3-Epoxyalcohols with Diethylaluminum Azide.
β Scribed by F. BENEDETTI; F. BERTI; S. NORBEDO
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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Regio-and Stereoselective Ring Openings of Unsymmetrical Oxatricyclo Adducts. -The cycloadducts (I), (IV), (VII), and (X) are amenable to SN2' ring opening by organolithium reagents. Primary, secondary, and tertiary organolithium reagents effect the ring-opening reaction, while methyllithium requir