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ChemInform Abstract: Regio- and Stereoselective Reaction of Chiral Alkoxy- and Aminomethyl-Substituted α-Silylallyl Carbanions with Aldehydes.

✍ Scribed by Li Liu; Dong Wang


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Regio- and Stereose
✍ M. YOSHIMATSU; J. HASEGAWA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB

Regio-and Stereoselective Vinylic Substitution Reactions of α-Haloenyne Sulfones. -A variety of alcoholates undergoes a nucleophilic vinylic substitution reaction with (E)-α-haloenyne sulfones such as (I) to yield the corresponding alkoxyenyne sulfones highly regioselectively. Attempted isomerizati