N-Allyl-N-(2-1ithioallyl)aniline undergoes intramolecular carbometallation via 5-exo addition on treatment with CuCN. 2-Alkenyl 2-bromophenyl ethers rearrange to 2-(2-alkenyl)pllenols by bromine-lithium exchange and further transmetallation with CuCN.
β¦ LIBER β¦
ChemInform Abstract: Regio- and Stereoselective Copper-Induced Isomerization of 2-Alkenyl 2- Lithiophenyl Ethers to 2-(2-Alkenyl)phenols.
β Scribed by J. BARLUENGA; R. SANZ; F. J. FANANAS
- Book ID
- 101858770
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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