ChemInform Abstract: Regio- and Stereochemical Aspects of the Palladium-Catalyzed Desilylation-Arylation of Substituted Vinylsilanes.

✍ Scribed by D. ALVISI; E. BLART; B. F. BONINI; G. MAZZANTI; A. RICCI; P. ZANI

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 31 KB
• Volume: 28
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199705099

✦ Synopsis

Regio-and Stereochemical Aspects of the Palladium-Catalyzed Desilylation-Arylation of Substituted Vinylsilanes.

-The presence of heteroatom-based functional groups in substituted vinylsilanes facilitates the Pd-catalyzed title reaction and appears to greatly affect the regiochemistry, probably through chelation-controlled reaction pathways. -(ALVISI, D.;